In this paper, the authors presented some research results on the various surface morphologies of polyaniline (PANi) film, directly synthesised on Pt/SiO2 interdigitated microelectrode area by electrochemical method. The outcomes of surface morphology and chemical composition structure analysis of PANi film were studied by Field-emission scanning electron microscopy (FE-SEM) and Fourier-transform infrared (FT-IR), respectively. The PANi film was fabricated with the nanowires (NWs) form with their diameter from 50÷100 nm. The length of several micrometers depends on aniline concentration and synthesis condition. The obtained consequences demonstrated that the PANi - NWs are fully potential objects for the detection of NH3 gas at room temperature.In this paper, the authors presented some research results on the various surface morphologies of polyaniline (PANi) film, directly synthesised on Pt/SiO2 interdigitated microelectrode area by electrochemical method. The outcomes of surface morphology and chemical composition structure analysis of PANi film were studied by Field-emission scanning electron microscopy (FE-SEM) and Fourier-transform infrared (FT-IR), respectively. The PANi film was fabricated with the nanowires (NWs) form with their diameter from 50÷100 nm. The length of several micrometers depends on aniline concentration and synthesis condition. The obtained consequences demonstrated that the PANi - NWs are fully potential objects for the detection of NH3 gas at room temperature.